Himmler, Aaron, Mohammed M. Albannay, Gevin von Witte, Sebastian Kozerke, and Matthias Ernst. “Electroplated Waveguides to Enhance DNP and EPR Spectra of Silicon and Diamond Particles.” Magnetic Resonance 3, no. 2 (October 6, 2022): 203–9.
https://doi.org/10.5194/mr-3-203-2022.
Electroplating the waveguide of a 7 T polarizer in a simple innovative way increased microwave power delivered to the sample by 3.1 dB. Silicon particles, while interesting for hyperpolarized MRI applications, are challenging to polarize due to inefficient microwave multipliers at the electron Larmor frequency at high magnetic fields and fast electronic relaxation times. Improving microwave transmission directly translates to more efficient EPR excitation at high-field, low-temperature conditions and promises faster and higher 29Si polarization buildup through dynamic nuclear polarization (DNP).